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Photodissociation Dynamics of the Ethoxy Radical (C 2 H 5 O) †

✍ Scribed by Choi, Hyeon; Bise, Ryan T.; Neumark, Daniel M.


Book ID
127310165
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
183 KB
Volume
104
Category
Article
ISSN
1089-5639

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Reactions of alkoxy radicals with O2. I.
✍ Steven Zabarnick; Julian Heicklen 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 899 KB

CzH50NO was photolyzed with 366 nm radiation at -48, -22, -2.5, 23, 55, 88, and 120°C in a static system in the presence of NO, 0,, and N,. The quantum yield of CH3CH0, (D{CH3CHO), was measured as a function of reaction conditions. The primary photochemical act is (la) CZHSONO + hv -\* CzH50 + NO an