Theoretical prediction of the fundamental properties for the ternary Li2PtH6 and Na2PtH6
✍ Scribed by M.A. Ghebouli; H. Choutri; N. Bouarissa; B. Ghebouli; A. Bouhemadou; F. Soyalp; E. Uçgun; H.Y. Ocak
- Book ID
- 118481634
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 754 KB
- Volume
- 196
- Category
- Article
- ISSN
- 0022-4596
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Li 2 PtH 6 , the missing member of the complex transition metal hydride series A 2 PtH 6 (A¼ alkali metal), was prepared by reacting mixtures of LiH and Pt in the presence of BH 3 NH 3 as hydrogen source at pressures above 8 GPa. According to powder X-ray diffraction analysis, Li 2 PtH 6 is isostruc
## Abstract The title compound is synthesized from mixtures of LiH and Pt in the presence of BH~3~NH~3~ (multi‐anvil device, <8 GPa, 450—500 °C, 60 min) and characterized by powder XRD and IR spectroscopy.
## Carbon disulphide inserts into the Pt-H bond oj trans-{PtH,[P(C~,1)3]2} to give trans-{PtH(S,CH) [P(CJ113J2}. The X-ray structure shows that the -S2CH group is bonded to the metal through a sulfur atom as a monodentate thioformate anion. The kinetics of the carbon disulfide insertion have been in