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The preparation of cis- and trans-[PtH(C6Cl5)(PEt3)2 and a study of the “hydride-donor capacity” of the complexes trans- [PtH(C6X5(PEt3)2] (X = F and Cl)

✍ Scribed by D. Carmona; S. Chaloupka; J. Jans; R. Thouvenot; L.M. Venanzi

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
745 KB
Volume
275
Category
Article
ISSN
0022-328X

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✍ Jaume Granell; Guillermo Muller; Mercè Rocamora; Jaume Vilarrasa 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 550 KB

=C and proton NMR spectra of several arylpalladium and some arylnickel and arylplatinum complexes have been compared. The Ni(PEt&X and Pd(PEt,),X substituents induce a paramagnetic shift of C,,, (of the phenyl ring) which is much larger than that induced by Pt(PEt,),X. However, there are no signific