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Theoretical (MM2) conformational analysis of 1,4-dioxepane

✍ Scribed by Entrena, A.; Jaime, C.; Espinosa, A.; Gallo, M. A.


Book ID
126783101
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
478 KB
Volume
54
Category
Article
ISSN
0022-3263

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## Abstract The 251 MHz ^1^H and the natural abundance 63.1 MHz ^13^C NMR spectra of 1,3‐dioxepane (1) and 4,4,7,7‐tetramethyl‐1,3‐dioxepane (2) have been investigated over the temperature range of 5 to βˆ’180 Β°C. While the spectra of 1 show no dynamic NMR effect, compound 2 exists in solution as a 1