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Theoretical investigation of the rovibrational fine-structure spectrum of ArNH in its electronic ground state

✍ Scribed by Georg Jansen; Bernal A. Hess; Paul E.S. Wormer

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
502 KB
Volume
214
Category
Article
ISSN
0009-2614

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✦ Synopsis

Based on an ab initio potential energy surface for the X 3A" ground state of the Ar-NH van der Waals complex its rovibrational fine-structure spectrum has been calculated. We find four Ar-NH stretching vibrational modes with the NH radical in a nearly unperturbed n-0 rotational state and one vibrational mode with NH in its first excited rotational level n= 1. The results are discussed and interpreted by means of pseudodiatomic model calculations.

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