Theoretical investigation of the atmospheric chemistry of methyl difluoroacetate: reaction with Cl atoms and fate of alkoxy radical at 298 K
β Scribed by Deka, Ramesh Chandra; Mishra, Bhupesh Kumar
- Book ID
- 125369409
- Publisher
- Springer
- Year
- 2014
- Tongue
- English
- Weight
- 838 KB
- Volume
- 25
- Category
- Article
- ISSN
- 1040-0400
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## Abstract Smog chamber/FTIR techniques were used to study the Cl atom initiated oxidation of CH~2~FOCH~2~F in 700 Torr of N~2~/O~2~ at 296 K. Relative rate techniques were used to measure __k__(Cl + CH~2~FOCH~2~F) = (4.6 Β± 0.7) Γ 10^β13^ and __k__(Cl + CH~2~FOC(O)F) = (2.9 Β± 0.8) Γ 10^β15^ (in un
Using a relative rate technique, rate constants have been determined for the gas-phase reactions of C1 atoms with the cholorethenes and ethane at 298 t 2 K and 735 torr total pressure of air. Using a rate constant of 1.97 x lo-'' cm3 molecule-' s-l for the reaction of C1 atoms with n-butane, the fol