Kinetic Investigation of the OH Radical and Cl Atom Initiated Degradation of Unsaturated Ketones at Atmospheric Pressure and 298 K
✍ Scribed by Blanco, María B.; Barnes, Ian; Wiesen, Peter
- Book ID
- 125935770
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 379 KB
- Volume
- 116
- Category
- Article
- ISSN
- 1089-5639
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## Abstract Rate constants for the reactions of OH radicals and Cl atoms with CH~3~ONO, C~2~H~5~ONO, __n__‐C~3~H~7~ONO, __n__‐C~4~H~9~ONO, and __n__‐C~5~H~11~ONO have been determined at 298 ± 2 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rat
Using a relative rate technique, rate constants have been determined for the gas-phase reactions of C1 atoms with the cholorethenes and ethane at 298 t 2 K and 735 torr total pressure of air. Using a rate constant of 1.97 x lo-'' cm3 molecule-' s-l for the reaction of C1 atoms with n-butane, the fol