Gas-phase reactivity study of a series of hydrofluoroolefins (HFOs) toward OH radicals and Cl atoms at atmospheric pressure and 298 K
✍ Scribed by Tovar, Carmen M.; Blanco, María B.; Barnes, Ian; Wiesen, Peter; Teruel, Mariano A.
- Book ID
- 125436210
- Publisher
- Elsevier Science
- Year
- 2014
- Tongue
- English
- Weight
- 718 KB
- Volume
- 88
- Category
- Article
- ISSN
- 1352-2310
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## Abstract Rate constants for the reactions of OH radicals and Cl atoms with CH~3~ONO, C~2~H~5~ONO, __n__‐C~3~H~7~ONO, __n__‐C~4~H~9~ONO, and __n__‐C~5~H~11~ONO have been determined at 298 ± 2 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rat
Using a relative rate technique, rate constants have been determined for the gas-phase reactions of C1 atoms with the cholorethenes and ethane at 298 t 2 K and 735 torr total pressure of air. Using a rate constant of 1.97 x lo-'' cm3 molecule-' s-l for the reaction of C1 atoms with n-butane, the fol