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Theoretical investigation of nature of δ31P chemical shift in phosphonium salts

✍ Scribed by A. S. Tarasevich

Book ID
112441536
Publisher
Springer
Year
1985
Tongue
English
Weight
722 KB
Volume
21
Category
Article
ISSN
0040-5760

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Three-bond 31P31P coupling and 31P chemi
Three-bond 31P31P coupling and 31P chemical shift effects in dimers of phospholium salts and phosphole oxides
✍ Louis D. Quin; Keith A. Mesch 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 197 KB

## Abstract The chemically nonequivalent ^31^P nuclei of the Diels‐Alder dimers of phospholium ions and phosphole oxides are coupled through three bonds by as much as 35–45 Hz. The chemical shift for a phosphorus atom in the 2‐phospholene moiety falls in the expected range; the shift for the constr