Dependence of chemical shift δ31P in phosphorus compounds on hybridization of bonding atoms of its alkyl substituents
✍ Scribed by A. S. Tarasevich
- Book ID
- 112529640
- Publisher
- Springer
- Year
- 1991
- Tongue
- English
- Weight
- 394 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-5760
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Phosphorus-31 NMR spectra were obtained+ on both syn and anti isomers of norbornenes with the 7-position bearing CI,P-, Me,P-, Me,(S)P-and Me,P as substituents. Norbornanes with 7-C12P-and 7-MezP-were also studied. Just as is true for 13C shits for 7-Me in these bicydo[2.2.l]heptane derivatives, the
The dependencies of Ka line shifts of the P and S atoms on effective charges of the atoms, calculated by CNDO/S, CNDOIZ, INDO, and MNDO methods in the minimal and extended basis sets, have been investigated for model compounds. Good linear relationships between Ka shifts and atomic charges have been