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The structure and δ31P chemical shifts of phosphazoalkanes [alkyliminophosphoranes]

✍ Scribed by Yu. P. Egorov; A. A. Kudryavtsev; A. M. Pinchuk; A. P. Marchenko; V. A. Kovenya

Book ID
112357377
Publisher
Springer
Year
1982
Tongue
English
Weight
692 KB
Volume
18
Category
Article
ISSN
0040-5760

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✍ Rosalinda Contreras; Jean Michel Grevy; Zureima García-Hernández; Marisol Göizad 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 244 KB

The isotope-induced chemical shifts 1 14/15 N( 31 P) were determined at natural abundance of 15 N by using HEED INEPT experiments. A dependence of 1 14/15 N( 31 P) on the substituents at nitrogen was found (alkyl < H < aryl; increasingly negative values). The magnitude and sign of the coupling const