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Theoretical investigation of a high density cage compound 1,3,5,7,9,11-hexanitrotetradecahydro-1H-1,3,4,5,7,7b,9,11,12a,12b1,12b2,13-dodecaaza-4,8,12-(epimethanetriyl)cyclohepta[l]cyclopenta[def] phenanthrene

✍ Scribed by Li Xiaohong, Cui Hongling, Zhang Xianzhou


Book ID
120779544
Publisher
Springer
Year
2012
Tongue
English
Weight
513 KB
Volume
24
Category
Article
ISSN
1040-0400

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2,8-Dimethoxy-4,10-dimethyl-1,3,7,9-tetr
✍ Bhuiyan, M. Delower H. ;Jensen, Paul ;Try, Andrew C. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 488 KB

In the molecule of the title compound, C~19~H~18~N~6~O~10~, the 2,8-dimethoxy-4,10-dimethyl-1,3,7,9-tetranitro analogue of Tröger's base, the diazocine bridge imparts a twist such that the two aryl rings are offset with respect to one another. The hinge angle of the molecule, measured as the dihedra