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The synthesis and stereochemistry of 5H-1,2,3,4,5a,12b-hexahydrocyclohepta[b]-10,11,12-trimethoxybenzo[d]thiepin-8(7H)-one

✍ Scribed by F. J. Lotspeich; S. Core


Book ID
112121947
Publisher
Journal of Heterocyclic Chemistry
Year
1969
Tongue
English
Weight
400 KB
Volume
6
Category
Article
ISSN
0022-152X

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2,8-Dimethoxy-4,10-dimethyl-1,3,7,9-tetr
✍ Bhuiyan, M. Delower H. ;Jensen, Paul ;Try, Andrew C. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 488 KB

In the molecule of the title compound, C~19~H~18~N~6~O~10~, the 2,8-dimethoxy-4,10-dimethyl-1,3,7,9-tetranitro analogue of Tröger's base, the diazocine bridge imparts a twist such that the two aryl rings are offset with respect to one another. The hinge angle of the molecule, measured as the dihedra