## Abstract The photoelectron spectra (PE.) of ten cyclophanes (**7** to **14, 16, 18**) have been assigned on the basis of a simple molecular orbital model proposed recently for the cyclophanes **2** (1,4) to **6**. It is shown that the agreement between calculated and observed band positions prov
Theoretical assignment of the vibronic bands in the photoelectron spectra of N2 below 30 eV
β Scribed by Miyabi Hiyama; Suehiro Iwata
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 731 KB
- Volume
- 211
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The relative luteusity of vibrational bands arIsing from phctolocization in 02 and 32 are examined as a function of angle. and the results dlscuvsed in terms 0: aul.oionization state6 and a possible breakdowu in the Bork&enhelmer approrcimatlon.
The high-resolution ( ~0.1 eV) inner valence photoelectron spectra of N2 and CO, with the binding energy in the 29-42 eV region are reported. For the first time, the effects of vibronic coupling are clearly resolved. Both spectra exhibit great complexity in structure. A preliminary assignment, based
The higher homologues of n-alkanes H(CH2),H with N > -13 yield photoelectron spectra in which the (&-bands merge to form a double humped, unresolved C2,-band system in the interval of I = 15 to 25 eV [l]. It is shown that with the help of an equivalent bond orbital model one can derive a closed form