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‘Through Space’ and ‘Through Bond’ Interactions in [2.2]Cyclopanes; the Assignment of their Photoelectron Spectra

✍ Scribed by Branka Kovač; Michael Allan; Edgar Heilbronner

Publisher
John Wiley and Sons
Year
1981
Tongue
German
Weight
931 KB
Volume
64
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The photoelectron spectra (PE.) of ten cyclophanes (7 to 14, 16, 18) have been assigned on the basis of a simple molecular orbital model proposed recently for the cyclophanes 2 (1,4) to 6. It is shown that the agreement between calculated and observed band positions provides strong evidence for the validity of the model.

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