Inner-shell singlet-triplet transitions in CO1 and NzO have been observed by the electron energy-loss technique at low values of the incident electron energy, typically 1.4 times the excitation energies of the states. The same technique has been used to observe fine structure in transitions near the
Fine structure in the inner valence photoelectron spectra of N2 and CO
โ Scribed by Z.F. Liu; G.M. Bancroft; L.L. Coatsworth; K.H. Tan
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 537 KB
- Volume
- 203
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The high-resolution ( ~0.1 eV) inner valence photoelectron spectra of N2 and CO, with the binding energy in the 29-42 eV region are reported. For the first time, the effects of vibronic coupling are clearly resolved. Both spectra exhibit great complexity in structure. A preliminary assignment, based on calculations which only considered the electronic excitations, is given.
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