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Theoretical Analysis of the Polymerization Kinetics of N-Carboxy-α-amino Acid Anhydrides

✍ Scribed by Katchalski, Ephraim; Shalitin, Yechiel; Gehatia, Matatiahu


Book ID
126943546
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
1002 KB
Volume
77
Category
Article
ISSN
0002-7863

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The polymerization of -y-benzyl+glutamate NCA initiated by n-hexylamine in DMF proceeds with two successive propagation r a h whose ratio is about 1.5. The onset of the increase in rate of propagation occurred a t a DP, of 7-14, which waa independent of initiator to anhydride ratio and anhydride con