High-resolution infrared spectra of the strong a-type absorptions corresponding to the n 1 (n 0 Ç 1310.75 cm 01 ) and n 2 (n 0 Å 821.9387 cm 01 ) bands of FNO 2 have been analyzed. The n 1 line positions exhibited extensive perturbations as a result of three nearly degenerate vibrational states-n 1
The ν4Band of FNO2
✍ Scribed by Charles E. Miller; Stanley P. S; er
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 179 KB
- Volume
- 181
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
The high-resolution infrared spectrum of nitryl fluoride, FNO 2 , has been observed in the 1750-1825 cm 01 region. The spectrum displays extensive rotational structure consisting solely of b-type transitions and is assigned to n 4 , the NO 2 antisymmetric stretching vibration. Over 1500 infrared and 51 microwave transitions have been fitted to generate rotational constants for the £ 4 Å 1 state (n 0 Å 1793.466822 cm 01 ) and improved constants for the ground state. Rotationally resolved infrared line positions are now available for the identification of FNO 2 , an atmospheric product of CFC and HFC oxidation.
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