𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The ν1, 2ν2, and 2ν3+ ν4Band System of Carbonyl Fluoride

✍ Scribed by Mark J.W. McPhail; Geoffrey Duxbury; Randy D. May

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
169 KB
Volume
182
Category
Article
ISSN
0022-2852

No coin nor oath required. For personal study only.

✦ Synopsis

The infrared spectrum of carbonyl fluoride, COF 2 , has been measured in the region from 1880 to 1980 cm 01 using a Bruker Fourier transform spectrometer at 0.003 cm 01 resolution and diode laser spectroscopy at Doppler-limited resolution. In this region the n 1 band at 1945 cm 01 dominates the spectrum and is in Fermi resonance with the 2n 2 band at 1914 cm 01 and in B-type Coriolis resonance with the 2n 3 / n 4 band at 1936 cm 01 . From the n 1 band, 820 lines were successfully fitted using an S-type Watson Hamiltonian in the III l representation, yielding rotational and fourth order centrifugal distortion constants, a Coriolis parameter of 0.00339(24) cm 01 , and an obs-calc RMS of 0.0006 cm 01 . Only 400 lines from 2n 2 could be successfully fitted, with an obs-calc RMS of 0.0005 cm 01 , because of interference from n 1 over much of the 2n 2 R branch.

📜 SIMILAR VOLUMES

H280Se: High-Resolution Study of the 2ν1
H280Se: High-Resolution Study of the 2ν1 + ν2, ν1 + ν2 + ν3, 3ν1, 2ν1 + ν3 and ν1 + 2ν3 Bands
✍ J.M. Flaud; C. Camypeyret; P. Arcas; H. Burger; H. Willner 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 449 KB

Using high-resolution Fourier transform spectra of monoisotopic \(\mathrm{H}_{2}{ }^{80} \mathrm{Se}\) recorded in the 1.8 and \(1.55-\mu \mathrm{m}\) regions. an extensive analysis of the \(2 \nu_{1}+\nu_{2}, \nu_{1}+\nu_{2}+\nu_{3}, 3 \nu_{1}, 2 \nu_{1}+\nu_{3}\), and \(\nu_{1}+\) \(2 v_{3}\) band

Line Positions and Intensities of the ν1
Line Positions and Intensities of the ν1+ ν2+ 3ν3, ν2+ 4ν3, and 3ν1+ 2ν2Bands of Ozone
✍ S. Mikhailenko; A. Barbe; Vl.G. Tyuterev; L. Regalia; J.J. Plateaux 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 272 KB

Using a Fourier transform spectrometer, we have recorded the spectra of ozone in the region of 4600 cm 01 , with a resolution of 0.008 cm 01 . The strongest absorption in this region is due to the n 1 / n 2 / 3n 3 band which is in Coriolis interaction with the n 2 / 4n 3 band. We have been able to a

The ν1+ ν2+ 2ν3and ν2+ 3ν3Bands of16O3
The ν1+ ν2+ 2ν3and ν2+ 3ν3Bands of16O3
✍ S. Bouazza; S. Mikhailenko; A. Barbe; L. Regalia; Vl.G. Tyuterev; J.J. Plateaux 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 178 KB

The infrared spectra of 16 O 3 have been recorded in the 3700 cm 01 region, with a Fourier transform spectrometer at 0.008 cm 01 resolution. A White-type cell, ᐉ Å 32.16 m, filled with 42.8 Torr O 3 was used. This spectral region corresponds to the n 2 / 3n 3 and n 1 / n 2 / 2n 3 bands. The n 2 / 3n

The ν2, ν4 + ν5, ν6 + ν9, and ν8 Band Sy
The ν2, ν4 + ν5, ν6 + ν9, and ν8 Band System in 1,1,1-Trifluoroethane
✍ Geoffrey Duxbury; Mark J.W. McPhail; Kevin M. Smith; Giandomenico Nivellini; Fra 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 86 KB

High-resolution FTIR spectra of 1,1,1-trifluoroethane (HFC-143a) have been recorded in the region from 1370 to 1470 cm Ϫ1 with an unapodized resolution of 0.0016 cm Ϫ1 at room temperature and of 0.004 cm Ϫ1 at 183 and 100 K. The two main infrared active bands of A 1 symmetry have been shown to be 2