𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The ν2, ν4 + ν5, ν6 + ν9, and ν8 Band System in 1,1,1-Trifluoroethane

✍ Scribed by Geoffrey Duxbury; Mark J.W. McPhail; Kevin M. Smith; Giandomenico Nivellini; Franca Tullini; Azzurra Celli

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
86 KB
Volume
199
Category
Article
ISSN
0022-2852

No coin nor oath required. For personal study only.

✦ Synopsis

High-resolution FTIR spectra of 1,1,1-trifluoroethane (HFC-143a) have been recorded in the region from 1370 to 1470 cm Ϫ1 with an unapodized resolution of 0.0016 cm Ϫ1 at room temperature and of 0.004 cm Ϫ1 at 183 and 100 K. The two main infrared active bands of A 1 symmetry have been shown to be 2 at 1407.5 cm Ϫ1 and 4 ϩ 5 at 1440.5 cm Ϫ1 . With the aid of Raman spectra, the two infrared inactive bands of E symmetry in this spectra region have been shown to be 8 at 1457.5 cm Ϫ1 and 6 ϩ 9 at 1446.2 cm Ϫ1 . The 2 band was analyzed as an isolated band, whereas the 4 ϩ 5 band was analyzed as part of the triad 4 ϩ 5 , 6 ϩ 9 , and 8 .

📜 SIMILAR VOLUMES

H280Se: High-Resolution Study of the 2ν1
H280Se: High-Resolution Study of the 2ν1 + ν2, ν1 + ν2 + ν3, 3ν1, 2ν1 + ν3 and ν1 + 2ν3 Bands
✍ J.M. Flaud; C. Camypeyret; P. Arcas; H. Burger; H. Willner 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 449 KB

Using high-resolution Fourier transform spectra of monoisotopic \(\mathrm{H}_{2}{ }^{80} \mathrm{Se}\) recorded in the 1.8 and \(1.55-\mu \mathrm{m}\) regions. an extensive analysis of the \(2 \nu_{1}+\nu_{2}, \nu_{1}+\nu_{2}+\nu_{3}, 3 \nu_{1}, 2 \nu_{1}+\nu_{3}\), and \(\nu_{1}+\) \(2 v_{3}\) band

The ν1, 2ν2, and 2ν3+ ν4Band System of C
The ν1, 2ν2, and 2ν3+ ν4Band System of Carbonyl Fluoride
✍ Mark J.W. McPhail; Geoffrey Duxbury; Randy D. May 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 169 KB

The infrared spectrum of carbonyl fluoride, COF 2 , has been measured in the region from 1880 to 1980 cm 01 using a Bruker Fourier transform spectrometer at 0.003 cm 01 resolution and diode laser spectroscopy at Doppler-limited resolution. In this region the n 1 band at 1945 cm 01 dominates the spec

Line Positions and Intensities of the ν1
Line Positions and Intensities of the ν1+ ν2+ 3ν3, ν2+ 4ν3, and 3ν1+ 2ν2Bands of Ozone
✍ S. Mikhailenko; A. Barbe; Vl.G. Tyuterev; L. Regalia; J.J. Plateaux 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 272 KB

Using a Fourier transform spectrometer, we have recorded the spectra of ozone in the region of 4600 cm 01 , with a resolution of 0.008 cm 01 . The strongest absorption in this region is due to the n 1 / n 2 / 3n 3 band which is in Coriolis interaction with the n 2 / 4n 3 band. We have been able to a

The {ν1+ 2ν2, ν1+ ν3} Bands of14N16O2: L
The {ν1+ 2ν2, ν1+ ν3} Bands of14N16O2: Line Positions and Intensities; Line Intensities in the ν1+ ν2+ ν3− ν2Hot Band
✍ J.-Y. Mandin; V. Dana; A. Perrin; J.M. Flaud; C. Camy-Peyret; L. Régalia; A. Bar 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 244 KB

High resolution Fourier transform absorption spectra of the 14 N 16 O 2 molecule recorded in the 2630-3510 cm 01 spectral region have been analysed and lines of the n 1 / n 3 band of this molecule have been assigned for K a values ranging from 0 to 10 and N values up to 55. The spin-rotation energy