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The ν2 bending mode infrared spectrum of clustered carbon dioxide

✍ Scribed by T.E. Gough; Tang-Yu Wang

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
401 KB
Volume
207
Category
Article
ISSN
0009-2614

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✦ Synopsis

The bendiq mode infrared spectrum of clusters of carbon dioxide formed in a diffusive trapping cell is reported. It is shown that, although the spectrum differs markedly from that reported for crystalline films of carbon dioxide, these differences may be attributed to effects generated by the size of the particle and the discontinuity in optical constants between the particle and its supporting buffer gas. It is concluded that the particles are crystalline; however, their morphology remains uncertain.

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