The lowest-frequency bending mode (ν71) of HCN-HF from near-infrared laser spectroscopy

Rovibrational analysis of the ν71 interm

Rovibrational analysis of the ν71 intermolecular hydrogen bond bending vibration in HCN---HF using far infrared fourier transform spectroscopy

✍ B.A. Wofford; R.S. Ram; A. Quinonez; J.W. Bevan; W.B. Olson; W.J. Lafferty 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 487 KB

Static gas phase far infrared Fourier transform spectroscopy has been applied to the observation of the low frequency intermolecular bending fundamental v: in the HCN---HF hydrogen-bonded complex. Rovibrational analysis of this band is reported giving the following molecular parameters (in cm-'): 8,