The γ-radiolysis of cyclobutane in the gas phase
✍ Scribed by E. Heckel; R.J. Hanrahan
- Publisher
- Elsevier Science
- Year
- 1973
- Weight
- 595 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0020-7055
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📜 SIMILAR VOLUMES
Identification of the radical species formed by -r-radiolysis of MlHF in the liquid phase was made by analysis of the ESR spectra observed from the spin-adducts of the radicals. A new secondary MlHF radical was found in addition to the tertiary radicaL
The gas phase iodination of cyclobutane was studied spectrophotometrically in a The early stage of the reaction static system over the temperature range 589" to 662°K. was found to correspond to the general mechanism where the Arrenius parameters describing kl are given by log kl/M-' sec-' = 1 1.
The phophorescence of bketyl induced by M energy transfer to biacetyl from triplet benzene produced in the pulse radiolysis GT benzene-bin&y1 mixtures hzs been s!udied. The time reqtiIed to reach the maximum intensity of phosphorescence, tmax, after the electron pulse, varies as a function of biacet