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2-methyl tetrahydrofuran radicals formed by γ-radiolysis in the liquid phase

✍ Scribed by S. Murabayashi; M. Shiotani; J. Sohma

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 294 KB
Volume: 48
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80218-2

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✦ Synopsis

Identification of the radical species formed by -r-radiolysis of MlHF in the liquid phase was made by analysis of the ESR spectra observed from the spin-adducts of the radicals. A new secondary MlHF radical was found in addition to the tertiary radicaL

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Kinetics of radiation-induced abstraction of hydrogen atoms by CCl3 radicals in the liquid phase: 2,3-dimethylbutane

✍ Zeev B. Alfassi; Liviu Feldman 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 325 KB 👁 1 views

## Abstract The kinetics of the gamma‐radiation induced free radical reactions in carbon tetrachloride solutions of 2,3‐dimethylbutane (DMB) were studied in the temperature range 32–118 °C. The kinetics of the following reactions were measured: and the following rate constants expression was obtai