✦ LIBER ✦

Phosphorescence of biacetyl sensitized by benzene in gas phase pulse radiolysis

✍ Scribed by Yoshihiko Hatano; Satoshi Takao; Takumi Ueno

Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 342 KB
Volume: 30
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(75)80024-8

No coin nor oath required. For personal study only.

✦ Synopsis

The phophorescence of bketyl induced by M energy transfer to biacetyl from triplet benzene produced in the pulse radiolysis GT benzene-bin&y1 mixtures hzs been s!udied. The time reqtiIed to reach the maximum intensity of phosphorescence, tmax, after the electron pulse, varies as a function of biacetyl pressure at constant benzene pressure (40 tort), which gives the lifetime of tripIet benzene T = (6.7 & 3.2) X 10V6 s and the rate constant of the energy transfer k&Bz(TI)+biacetyl = (1.6 * 0.7) X 1O-'o cm3 molecule-' S-I.

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