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THE YIELDS OF SOME GRIGNARD REAGENTS. ALTERNATING PROPERTIES OF NORMAL ALKYL BROMIDES

โœ Scribed by Gilman, Henry; Zoellner, E. A.; Dickey, J. B.

Book ID
120393925
Publisher
American Chemical Society
Year
1929
Tongue
English
Weight
564 KB
Volume
51
Category
Article
ISSN
0002-7863

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It has been established by chemical (2a) and CIDNP (3,4) techniques that some transition metal salts catalyze the reaction of Grignard reagents with alkyl halides by a mechanism involving free radicals. Such catalysis is probably responsible for the Wurtz coupling side reaction which lowers the yiel