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THE REDUCING ACTION OF THE GRIGNARD REAGENT. II. COMPARISON WITH THE EASE OF REMOVAL OF HYDROGEN BROMIDE FROM ALKYL BROMIDES AND WITH THE AMOUNT OF DIALKYLMAGNESIUM IN THE GRIGNARD REAGENT

โœ Scribed by Noller, C. R.; Hilmer, F. B.

Book ID
127242700
Publisher
American Chemical Society
Year
1932
Tongue
English
Weight
273 KB
Volume
54
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

The role of impurities in the reactions
The role of impurities in the reactions of grignard reagents with alkyl bromides
โœ Richard B. Allen; Ronald G. Lawler; Harold R. Ward ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 193 KB

It has been established by chemical (2a) and CIDNP (3,4) techniques that some transition metal salts catalyze the reaction of Grignard reagents with alkyl halides by a mechanism involving free radicals. Such catalysis is probably responsible for the Wurtz coupling side reaction which lowers the yiel