𝔖 Bobbio Scriptorium
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The vinylcyclopropane rearrangement: An AM1 study

✍ Scribed by J.J. Quirante; F. Enriquez; J.M. Hernando


Book ID
113257085
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
485 KB
Volume
204
Category
Article
ISSN
0166-1280

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📜 SIMILAR VOLUMES


Diradicals in the vinylcyclopropane rear
✍ G.W. Klumpp; M. Schakel 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 205 KB

Product ratios and their insensitivity to steric effects indicate the title reactions to occur through diradicals with limited rotational freedom. Tne mechanism of the thermal vinylcyclopropane rearrangement is still a matter of contr0versy.l The absence of steric effects that might be caused by sub