𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A kinetic study of the thermal rearrangement of 2-(trifluoromethyl)-1-vinylcyclopropane

✍ Scribed by William R. Dolbier Jr.; Martin A. McClinton


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
396 KB
Volume
70
Category
Article
ISSN
0022-1139

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Kinetic study of the thermal rearrangeme
✍ Nick M. Vandewiele; Kevin M. Van Geem; Marie-FranΓ§oise Reyniers; Guy B. Marin πŸ“‚ Article πŸ“… 2011 πŸ› Elsevier Science 🌐 English βš– 446 KB

Pyrolysis of cis-and trans-2-pinanol is performed in a temperature range from 753 K to 843 K and conversions ranging from 10 to 96%. Kinetic models for the pyrolysis of both diastereomers are presented. Good agreement between simulated and experimental data was achieved in all cases. The reactivity

Thermal Rearrangements, XIX. The Kinetic
✍ Hopf, Henning ;Wachholz, Gerhard ;Walsh, Robin ;de Meijere, Armin ;Teichmann, St πŸ“‚ Article πŸ“… 1989 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 515 KB

B 371 1 -Ethynyl-2,2,3,3-tetramethylcyclopropane (9) has been prepared and subjected to gas phase pyrolysis. Above 200Β°C the hydrocarbon rearranges to 4,4,5-trimethyl-I ,2,5-hexatriene (10) and 5,6dimethyl-5-hepten-I-yne (11). Whereas the allene is produced directly from 9 by a 1,Shydrogen shift, th

A kinetic investigation of the thermal r
✍ H.P. Figeys; R. Jammar πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 241 KB

The first-order rate constants of the thermal rearrangement of several N-pyridino-2-vinyl-aziridines into the corresponding pyrido-azepines have been determined. Substituent effects on this isomerization were found to be completely analogous to the related benzenic 0-Claisen rearrangement.