𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Gas-Phase Kinetics of the Thermal 1-Alkoxy-1-vinylcyclopropane to 1-Alkoxy-1-cyclopentene Rearrangement

✍ Scribed by McGaffin, Gregory ;Meijere, Armin De ;Walsh, Robin


Publisher
Wiley (John Wiley & Sons)
Year
1991
Tongue
English
Weight
678 KB
Volume
124
Category
Article
ISSN
0009-2940

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Thermal Rearrangements, XX[1] The Kineti
✍ Hopf, Henning ;Wachholz, Gerhard ;Walsh, Robin 📂 Article 📅 1992 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 931 KB

4‐Methyl‐1,2,5‐hexatriene (13) has been prepared and subjected to gas‐phase pyrolysis. Above 220°C, 13 rearranges reversibly to both __trans__‐5‐hepten‐1‐yne (14) and its __cis__‐isomer 15. Formation of 14 is faster than that of 15. These isomerisations are accompanied by a slower irreversible rearr

Kinetics of the thermal gas-phase isomer
✍ M. C. Flowers; D. E. Penny; J.-C. Pommelet 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 425 KB

## Abstract The kinetics of the gas‐phase decomposition of 1,2‐epoxycyclohexane has been studied over the temperature range 680–740 K at pressures between 1.6 and 6 torr. Isomerization to cyclohexanone and 2‐cyclohexen‐1‐ol accounts for ca. 97% of the primary reaction products and occurs by first‐o

The kinetic and mechanism of the gas pha
✍ Rosa M. Domínguez; Gabriel Chuchani 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 331 KB

The gas phase pyrolysis of 1,1,1,2-tetrachloropropane was studied in a ,static system and seasoned vessel over the temperature range of 393.0-452.8"C and pressure range of 27.5-1 18.5 torr. The reaction is homogeneous, unimolecular, follows a first-order rate law, and is not affected by the presence

Kinetics of the thermal gas phase isomer
✍ M. C. Flowers; D. E. Penny 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 341 KB

## Abstract The kinetics of the gas‐phase decomposition of bicyclo[4.1.0]heptane has been studied over the temperature range of 708–769 K at pressures between 1 and 17 torr. Isomerization to 1‐methylcyclohex‐1‐ene, methylenecyclohexane, and cycloheptene accounts for 96–98% of the primary reaction p

Kinetics of the thermal gas phase reacti
✍ M. C. Flowers; R. M. Parker 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 English ⚖ 461 KB

The kinetics of the gas phase decomposition of 1,2-epoxy-2-methylpropane has been studied over the temperature range 377"-436°C at pressures between 5.3 and 61.6 torr. Isomerization reactions to give isobutyraldehyde, isopropenyl methyl ether, and P-methylprop-2-en-1-01 account for over 95% of the e