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Kinetics of the thermal gas phase isomerization of bicyclo[4.1.0]heptane

✍ Scribed by M. C. Flowers; D. E. Penny

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
341 KB
Volume
5
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The kinetics of the gas‐phase decomposition of bicyclo[4.1.0]heptane has been studied over the temperature range of 708–769 K at pressures between 1 and 17 torr. Isomerization to 1‐methylcyclohex‐1‐ene, methylenecyclohexane, and cycloheptene accounts for 96–98% of the primary reaction products and occurs by first‐order, homogeneous, nonradical processes.

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