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Kinetics of the thermal gas-phase isomerization of 1,2-epoxycyclohexane

✍ Scribed by M. C. Flowers; D. E. Penny; J.-C. Pommelet

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
425 KB
Volume
5
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The kinetics of the gas‐phase decomposition of 1,2‐epoxycyclohexane has been studied over the temperature range 680–740 K at pressures between 1.6 and 6 torr. Isomerization to cyclohexanone and 2‐cyclohexen‐1‐ol accounts for ca. 97% of the primary reaction products and occurs by first‐order, homogeneous, nonradical processes:

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