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A kinetic investigation of the thermal rearrangement of N-pyridino-2-vinyl-aziridines.

โœ Scribed by H.P. Figeys; R. Jammar

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
241 KB
Volume
22
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The first-order rate constants of the thermal rearrangement of several N-pyridino-2-vinyl-aziridines into the corresponding pyrido-azepines have been determined. Substituent effects on this isomerization were found to be completely analogous to the related benzenic 0-Claisen rearrangement.

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## Abstract Several samples of poly(vinyl formal) having the same vinyl alcohol content (8โ€“9%) but varying contents of vinyl acetate (6โ€“22%) and vinyl formol (70โ€“85%) were prepared and subjected to thermogravimetric analysis, in air and nitrogen atmospheres, employing both isothermal and dynamic me