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Direct Dynamics Quasiclassical Trajectory Study of the Stereochemistry of the Vinylcyclopropane−Cyclopentene Rearrangement

✍ Scribed by Doubleday, Charles; Nendel, Maja; Houk, K. N.; Thweatt, David; Page, Michael


Book ID
125977270
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
39 KB
Volume
121
Category
Article
ISSN
0002-7863

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Stereochemical studies on the palladium-catalyzed asymmetric 1,3rearrangements of [4-chiral arylsulfinyl-1,3(E or Z)-butadienyl]cyclopropanes to chiral cyclopentenes are described. The plausible mechanism for the rationalization of the stereochemical outcomes is proposed.