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The mechanism of photochemical rearrangement of vinylcyclopropanes to cyclopentenes

✍ Scribed by Ming-Der Su


Book ID
107857540
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
216 KB
Volume
51
Category
Article
ISSN
0040-4020

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Thermal isomerizations of vinylcycloprop
✍ Baldwin, John E. πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 298 KB

The thermal isomerization of vinylcyclopropane to cyclopentene was discovered in 1960 and soon recognized as the simplest known example of w x a 1,3 sigmatropic shift. Experimental observations for the parent rearrangement and for isomerizations shown by substituted systems suggest that diradical tr