Thermal isomerizations of vinylcycloprop
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Baldwin, John E.
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Article
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1998
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John Wiley and Sons
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English
β 298 KB
The thermal isomerization of vinylcyclopropane to cyclopentene was discovered in 1960 and soon recognized as the simplest known example of w x a 1,3 sigmatropic shift. Experimental observations for the parent rearrangement and for isomerizations shown by substituted systems suggest that diradical tr