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Stereochemistry of the Thermal Isomerization of Vinylcyclopropane to Cyclopentene

✍ Scribed by Baldwin, John E.; Villarica, Karla A.; Freedberg, Daron I.; Anet, Frank A. L.


Book ID
127080619
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
189 KB
Volume
116
Category
Article
ISSN
0002-7863

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Thermal isomerizations of vinylcycloprop
✍ Baldwin, John E. πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 298 KB

The thermal isomerization of vinylcyclopropane to cyclopentene was discovered in 1960 and soon recognized as the simplest known example of w x a 1,3 sigmatropic shift. Experimental observations for the parent rearrangement and for isomerizations shown by substituted systems suggest that diradical tr