The vibrational spectra of several ethyl chlorides: CH3CH2Cl, CH3CD2Cl, CD3CH2Cl, and CD3CD2Cl
β Scribed by Foil A. Miller; F.E. Kiviat
- Book ID
- 113372221
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- English
- Weight
- 1002 KB
- Volume
- 25
- Category
- Article
- ISSN
- 1386-1425
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The I3C shielding of the isotopomers CH,Cl, CH,DCl, CHD,Cl, and CD,C1 has been calculated for a range of temperatures from an self-consistent field (SCF) shielding surface computed by Buckingham and Olegario. It is found that each successive deuterium substitution increases the shielding by about 0.
The abstraction of hydrogen/deuterium from CH3CH2C1, CH,CHDCl, and CH,CD,Cl by photochemically generated ground-state chlorine atoms has been investigated over the temperature range of 8-94Β°C using methane as a competitor. Rate constant data for the following reactions have been obtained: (1) CH,C&C
The occurrence and magnitude of secondary kinetic isotope effects in the gas phase has been detcrmmcd for deuterium abstraction from the CD3 group in CD$ZH$l. CD$HDCI. and CD-&D&l by phorochemically generated \_eroundstaxe chlorine aloms. Over the temperature range lo-94Β°C a discernible "inverse" ki