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The vibrational deactivation of the bending modes of CD4 and CH4 measured down to 90 K

โœ Scribed by R.M. Siddles; G.J. Wilson; C.J.S.M. Simpson


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
661 KB
Volume
188
Category
Article
ISSN
0301-0104

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๐Ÿ“œ SIMILAR VOLUMES


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## Energy transfer between vibrationally excited CO and COz has been used to excite the bendini mode of COa. The rate of deactivation of this mode by CO\* and by Ar has been measured down to 150 K. The followรฏng processes were considered CO@= 1) + co,(ooo) Ke 5 CO(u=O) + CO,(OOl), AE = t206 crneL

The measurement of rate constants for th
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Rate constants for the vibrational deactivation of 12C1b by Hz, Dz and 'He have been determined by laser-induced fluorescence in the gas phase at low temperatures. The rate constants for 12C160( u= 1 )-H2 and '\*C?O( u= 1 )-D2 have been measured down to 35 K and those for '\*C%(o= 1 )-'He have been

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Probabilities for the (VT) and (VR) deactivation of CO have been calculated from relaxation times measured down to 77 K using laser fluorescence. Only in the case of deactivation by p-H2 is the (VR) process important; its rate exceeds that for (VT) deactivation between 320 K and 110 K.