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The vacuum ultraviolet spectra of methylvinylsilane and propylene

โœ Scribed by A.A. Iverson; B.R. Russell; Paul Ronald Jones

Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
254 KB
Volume
17
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The VW spectra of methylvinylsilane and propylene are reported and corresponding transitions are assigned. The small red shift of the w-r* transition and the Inve blue shift of the CT-O* excitation of the methyl group in mcthylvinylsiianc may bc attributed to the +I inductive cffcct of silicon without involving interaction between d orbitals and the n system. No cvidcnce for a second allowed TTTT* transition is found in methylvinylsilane.

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