The VW spectra of methylvinylsilane and propylene are reported and corresponding transitions are assigned. The small red shift of the w-r\* transition and the Inve blue shift of the CT-O\* excitation of the methyl group in mcthylvinylsiianc may bc attributed to the +I inductive cffcct of silicon wit
The vacuum ultraviolet spectra of methylated silanes
โ Scribed by A.G. Alexander; O.P. Strausz; R. Pottier; G.P. Semeluk
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 136 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0009-2614
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The vacuum-ultraviolet spectra from 200 to 120 nm of BFJ, BC13 and BDrs are reported. Tentative assignments are made. The lowest frcqucncy band of DC13 and BBr3 can be assigned to a valence-shell transition of the ?I\* + n type. The second band can be described equnll?r well 3s a Rydberg tr~lsition
&ported are the vapo$ phase spectra Of Cr(CO)S, bIo(CO)+ w(CO)G at 300ยฐK in thk? VaCWm U.kIXviolet region 2200 -1250 A. Several new transitions are seen with preliminary interpretations in terms of a simple bond-exciton model and compared with some recent photoionization studies.