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The UV absorption spectrum of trimethylsilyl radical in the gas phase

✍ Scribed by Nobuo Shimo; Nobuaki Nakashima; Keitaro Yoshihara

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
291 KB
Volume
125
Category
Article
ISSN
0009-2614

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✦ Synopsis

The UV absorption spectrum of trimethylstlyl radical was observed at 256 nm for the first time by photolysing allyltrimethylsilane and hexamethyldisilane with an ArF excimer laser. A bimolecular rate constant for recombination of trimethylsilyl radical of (2.5 +0.5)X10-" molecule-' cm3 s-' was measured.

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