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Infrared absorption spectrum of t-butylperoxy radicals in the gas phase

✍ Scribed by D.A. Parkes; R.J. Donovan

Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 325 KB
Volume: 36
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(75)87017-5

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✦ Synopsis

Two transient absorptions have been detected in the infrared region during the gas-phase photolysis of azoisobutane/O:! mhtures nt 293 K. These transitions centred at 693.7 i 0.5 cm-' and 760 f 2 cm-' are assiged to the I-butylperoxy radical. A simple flow system at atmospheric piessure was used together with B multiple pass cell.

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