The UV absorption spectrum and geometry of the HS2 radical
β Scribed by R.K. Gosavi; M. DeSorgo; H.E. Gunning; O.P. Strausz
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 814 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0009-2614
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Chemiluminescence from electronitiy excited HS2 radi&s has be&n detected between 950 and 2100 nm in gas-pha;9 flow systems. The emission essentially consits of u:sequences of the I$ (Al 'A' -t x 'A") tra&iion wi& the 000 -000 lxmd origin at 1378 nm. DS2 was also studied For HSp the following spectro
The UV absorption spectrum of trimethylstlyl radical was observed at 256 nm for the first time by photolysing allyltrimethylsilane and hexamethyldisilane with an ArF excimer laser. A bimolecular rate constant for recombination of trimethylsilyl radical of (2.5 +0.5)X10-" molecule-' cm3 s-' was measu
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