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The Use of Adiabatic Calorimetry for the Process Analysis and Safety Evaluation in Free Radical Polymerization

✍ Scribed by G. Maschio; J. A. Feliu; J. Ligthart; I. Ferrara; C. Bassani

Book ID
110287298
Publisher
Springer Netherlands
Year
1999
Tongue
English
Weight
754 KB
Volume
58
Category
Article
ISSN
0022-5215

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Evaluation of propagation rate constants
Evaluation of propagation rate constants for the free radical polymerization of methacrylonitrile by pulsed laser photolysis
✍ Devon A. Shipp; Trevor A. Smith; David H. Solomon; Graeme Moad πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 411 KB

## Abstract Propagation rate constants for the free radical polymerization of methacrylonitrile (MAN) have been obtained by pulsed laser photolysis (PLP). The temperature dependence of the propagation rate constants indicates a frequency factor of 10^(6,43 Β± 0,26)^ L Β· mol^βˆ’1^ Β· s^βˆ’1^ and an activa