Evaluation of the Chain Length Distribution in Free-Radical Polymerization, 2. Emulsion Polymerization
✍ Scribed by Alessandro Butté; Giuseppe Storti; Massimo Morbidelli
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 231 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1022-1344
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📜 SIMILAR VOLUMES
## M - w vs conversion for several experiments. Also shown are linear fits to the asymptotically linear portion described by the QSSA.
A new solution for chain-length distributions of "dead" polymer and their moments (obtained by solving the coupled system of non-linear differential equations in full generality) is presented and compared to existing theoretical and numerical approaches. The new solution for chain-length distributio
Free-radical polymerization of styrene was carried out in the presence of chain transfer agents (CTAs) with functionality, f ϭ 1-4. The size exclusion chromatography (SEC) with an ultraviolet absorption detector (UV) was used to measure the molecular weight distribution (MWD). A Monte Carlo simulati