Observation and analysis of a slow termination process in the atom transfer radical polymerization of styrene
โ Scribed by Krzysztof Matyjaszewski; Kelly Davis; Timothy E. Patten; Mingli Wei
- Book ID
- 108378762
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 518 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0040-4020
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๐ SIMILAR VOLUMES
Well-deยฎned polystyrenes with an a-C(CH 3 ) 2 (CN) and an v-chlorine atom end-groups, and narrow polydispersity (M n = 3000ยฑ4000 g mol ร1 , M w /M n = 1.3ยฑ1.4) have been synthesized by a radical polymerization process using 2,2'-azobisisobutyronitrile(AIBN)/FeCl 3 /PPh 3 initiation system. When the
## Abstract Commercially available poly(ethylene oxide) macromonomers are successfully used as reactive stabilizers for atom transfer radical dispersion/precipitation polymerization of styrene. Polystyrene particles with PEO chains covalently anchored on the surfaces are obtained. Control over both
## Abstract Kinetic simulations using the composite __k__~t~ model allows a better understanding of the effects of the persistent radical affecting ATRP or for that matter any activationโdeactivation system. It also provides a better fit to experimental data in either bulk or solution conditions fo