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The unimolecular thermal decomposition mechanism of syn, anti-N,N′-Dinitrourea (DNU)

✍ Scribed by Long Liu; Kun Dong; Xiaoqian Yao; Zengxi Li; Chunshan Li; Jian Sun; Xiangping Zhang; Suojiang Zhang

Book ID
113550767
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
556 KB
Volume
159
Category
Article
ISSN
0010-2180

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The kinetics and mechanism of the thermal decomposition of n-propylsilane have been studied by the single pulse shock tube-comparative rate technique a t pressures around 4700 torr between 1095-1240 K. The primary dissociation processes are 1,l and 1,2 H, elimination with &,,, = 0.75 and &,,\* = 0.2