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Syn-anti isomerism in an N-benzenesulfonylimine. Mechanism of stereomutation at the carbon-nitrogen double bond

โœ Scribed by Raban, Morton; Carlson, Eric


Book ID
111925188
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
827 KB
Volume
93
Category
Article
ISSN
0002-7863

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syn-anti-Isomerism at the Carbon-Sulfur
โœ Priv.-Doz. Dr. Horst Kessler; Hans-Otto Kalinowski ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 218 KB

respectively, in about 50 yield by reaction with di(p-nitrophenyl) phosphorochloridate 151. Whereas (56) is obtained directly (55 % yield) on treatment of (26) with 1 N NaOH/methanol (1 :1) in 100 h at room temperature, (5a) can only be synthesized stepwise. As first step, one p-nitrophenol group i