The unexpected fixation of CO2 employing a CuIBr(bpy)2 complex
โ Scribed by Kickelbick, Guido
- Publisher
- International Union of Crystallography
- Year
- 2001
- Tongue
- English
- Weight
- 363 KB
- Volume
- 57
- Category
- Article
- ISSN
- 1600-5368
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โฆ Synopsis
Single-crystal X-ray study T = 293 K Mean '(CยฑC) = 0.012 A ร R factor = 0.047 wR factor = 0.110 Data-to-parameter ratio = 8.2
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## Abstract The new Hโbonded complex [Os(bpy)~2~(CO)(EtOยทยทยทHโDMAP)][PF~6~]~2~, where DMAP = 4โ(dimethylamino)pyridine and bpy = 2,2โฒโbipyridine, has been synthesized and characterized by Xโray diffraction, IR, solution and solidโstate NMR spectroscopy. The complex shows a strong hydrogen bond betwe