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Electrochemical characterization of [RuII(bpy)(CO)2Cl2] (bpy = 2,2'-bipyridine): Isolation of a new complex: [RuII(bpy)(CO)Cl2][Me4N]

✍ Scribed by Marie-Noëlle Collomb-Dunand-Sauthier; Alain Deronzier; Raymond Ziessel


Publisher
Elsevier Science
Year
1991
Weight
461 KB
Volume
319
Category
Article
ISSN
0022-0728

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Novel Complexes trans(Cl)-[Os(bpy)(CO)(C
✍ Sylvie Chardon-Noblat; Philippe Da Costa; Alain Deronzier; Taasje Mahabiersing; 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 139 KB 👁 1 views

Photoirradiation of the complex trans(Cl)-[Os(bpy)(CO) 2 Cl 2 ] in acetonitrile with λ Ն 320 nm light gives rise to substitution of a CO ligand, with the formation of trans(Cl)-[Os(bpy)-(CO)(CH 3 CN)Cl 2 ]. The bonding properties and redox reactions of the novel photoproduct were thoroughly investig